Cover...................................................... i Preface....................................................iii Summary of the work........................................ iv Table of Contents.......................................... v Illustrations..............................................vii INTRODUCTION Foundation and early annals of the astrophysical observatory.............................................. 1 PART I The absorption lines in the infra-red spectrum of the sun.. 5 Chapter I.--Historical account of contributory researches.. 7 Early investigations....................................... 7 The writer's early work at Allegheny....................... 10 Recent investigations of infra-red spectra by others than the writer................................................. 19 Chapter II.--The present research.......................... 22 Account of the progress of the investigations at the Smithsonian Astrophysical Observatory.................... 22 Condition of the research July 1, 1892..................... 23 Progress of the research in the year ending July 1, 1893... 27 Progress of the research in the year ending July 1, 1894... 30 Progress of the research in the year ending July 1, 1895... 35 Progress of the research in the year ending July 1, 1896... 38 Progress of the research in the year ending July 1, 1897... 39 Chapter III.--Description of the observatory buildings and the apparatus employed in the research -- adjustments of apparatus................................................ 40 The observatory............................................ 40 Apparatus.................................................. 43 Constants of the electrical system....................... 43 Constants of the optical system.......................... 45 Siderostat............................................... 45 Slit..................................................... 46 Spectrometer and accessories............................. 46 Bolometer and accessories................................ 47 Driving clock............................................ 56 Plate carrier............................................ 58 Galvanometer and accessories............................. 59 Battery.................................................. 63 Comparator............................................... 64 Adjustment of apparatus.................................... 65 Siderostat............................................... 65 Slit..................................................... 65 Mirror system............................................ 65 Prism.................................................... 66 Cylindric lens........................................... 67 Chapter IV.--Methods of procedure in preparing and comparing bolographs..................................... 69 The bolographic processes.................................. 69 1. Preparing the curves.................................. 69 2. Methods of identification of absorption lines......... 71 Conversion of bolometric curves to linear spectra.......... 73 Comparison and measurement of bolographs to discriminate and fix the position of "real" inflections............... 74 Chapter V.--Limitations of the research-sources of error now existing............................................. 76 Limitations of the research................................ 76 1. Visual resolving power of the prism................... 76 2. Slit width............................................ 77 3. Collimation........................................... 77 4. Bolometric resolution................................. 82 Sources of error........................................... 85 I. Optical apparatus................................... 86 II. Accidental deflections in record curves.............105 III. Imperfect mechanism.................................112 IV. Preparing linear spectra from bolographs............116 V. Comparator measurements.............................118 VI. Inherent in the bolographic method..................119 Summary of results of limitations and errors...............122 A. Limitations...........................................122 B. Errors................................................123 Chapter VI.--The absorption lines in the infra-red solar spectrum; results of bolographic spectrum analysis in 1897-98..................................................126 Illustrations..............................................127 Comparison of bolographs...................................129 Notes accompanying bolographs..............................133 Measurements on bolographs.................................137 Reduction of observations..................................171 Tables of final values.....................................176 Comparison of the results with the solar spectrum maps of Higgs and Abney and with infra-red metallic lines of Snow, Lewis, and others..................................200 Chapter VII.--The variations of absorption in the infra-red solar spectrum.............................................205 Typical energy curves....................................206 Irregular variations of absorption.......................207 Emission and absorption experiments......................215 Summary..................................................216 PART II Subsidiary researches......................................217 Chapter I.--The dispersion of rock salt and fluorite.......218 The relative dispersion of rock salt and fluorite..........218 The dispersion of rock salt................................222 Have all rock-salt prisms the same indices of refraction?..236 Chapter II.--Miscellaneous observations....................238 1. The accuracy of the bolometer...........................238 2. Radiation from terrestrial sources......................240 Supplementary note.........................................242 Chapter III.--Construction of a sensitive galvanometer.....244 Purposes for which it was constructed......................244 Considerations governing the construction..................245 Best construction of coils.................................248 The needle system..........................................251 Summary....................................................252 APPENDIX The determination of wave-lengths in the infra-red spectrum of rock salt....................................253 The constants for rock salt in Ketteler's dispersion formula....................................................261 The minute structure of the absorption band omega..........263 Index......................................................265